Chemical Reactions and Equations

Notes on Chapter 1: Chemical Reaction and Equations

1. Chemical Reactions: Fundamental Characteristics

A chemical reaction represents a profound transformation where reactants change into products, fundamentally altering the nature and identity of substances.

Key Indicators of a Chemical Reaction

2. Representing Chemical Reactions

Chemical reactions can be represented through two primary notation systems:

Word Equation: Magnesium + Oxygen → Magnesium oxide
Chemical Equation: Mg + O₂ → MgO

3. Balancing Chemical Equations

The law of conservation of mass states that mass is neither created nor destroyed in a chemical reaction. Therefore, the number of atoms of each element must be the same on both sides of the equation. An unbalanced equation (skeletal equation) must be balanced using coefficients. For example:

Unbalanced Equation: Fe + H₂O → Fe₃O₄ + H₂
Balanced Equation: 3Fe + 4H₂O → Fe₃O₄ + 4H₂

Balancing involves a methodical hit-and-trial approach, carefully adjusting coefficients to equalize atomic counts.

4. Types of Chemical Reactions

Reaction Categories

5. Energy in Chemical Reactions

Heat Transfer Characteristics

Chemical Reactions Classification

Exothermic Reactions

No. Reaction Equation
1 Combustion of methane CH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(g) + heat
2 Neutralization of acid and base HCl(aq) + NaOH(aq) → NaCl(aq) + H₂O(l) + heat
3 Respiration C₆H₁₂O₆(aq) + 6O₂(g) → 6CO₂(g) + 6H₂O(l) + energy
4 Reaction of calcium oxide with water CaO(s) + H₂O(l) → Ca(OH)₂(aq) + heat

Endothermic Reactions

No. Reaction Equation
1 Photosynthesis 6CO₂(aq) + 6H₂O(l) + energy → C₆H₁₂O₆(aq) + 6O₂(g)
2 Decomposition of calcium carbonate CaCO₃(s) + heat → CaO(s) + CO₂(g)
3 Electrolysis of water 2H₂O(l) + energy → 2H₂(g) + O₂(g)
4 Photodecomposition of silver chloride 2AgCl(s) + light → 2Ag(s) + Cl₂(g)

Detailed Practical Activities

Activity 1.3: Zinc and Dilute Acid Reaction

Procedure: Add zinc granules to dilute hydrochloric or sulfuric acid in a conical flask.

Observations:

Reaction: Zn + 2HCl → ZnCl₂ + H₂

Type: Displacement Reaction (Exothermic)

Activity 1.4: Formation of Slaked Lime

Procedure: Mix calcium oxide (quick lime) with water

Observations:

Reaction: CaO + H₂O → Ca(OH)₂

Type: Combination Reaction (Exothermic)

Activity 1.5: Decomposition of Ferrous Sulphate

Procedure: Heat ferrous sulphate crystals in a boiling tube

Observations:

Reaction: 2FeSO₄ → Fe₂O₃ + SO₂ + SO₃

Type: Thermal Decomposition Reaction

Activity 1.6: Decomposition of Lead Nitrate

Procedure: Heat lead nitrate powder in a boiling tube

Observations:

Reaction: 2Pb(NO₃)₂ → 2PbO + 4NO₂ + O₂

Type: Thermal Decomposition Reaction

Activity 1.7: Electrolysis of Water

Procedure: Electrolysis of water with dilute sulfuric acid using carbon electrodes

Observations:

Reaction: 2H₂O → 2H₂ + O₂

Type: Electrolytic Decomposition Reaction

Activity 1.8: Photodecomposition of Silver Chloride

Procedure: Expose silver chloride to sunlight in a china dish

Observations:

Reaction: 2AgCl → 2Ag + Cl₂

Type: Photodecomposition Reaction (Used in black-and-white photography)

Activity 1.9: Displacement Reaction with Iron and Copper Sulphate

Procedure: Immerse iron nails in copper sulfate solution for 20 minutes

Observations:

Reaction: Fe + CuSO₄ → FeSO₄ + Cu

Type: Displacement Reaction

Activity 1.10: Double Displacement Reaction

Procedure: Mix sodium sulfate and barium chloride solutions

Observations:

Reaction: Na₂SO₄ + BaCl₂ → BaSO₄ + 2NaCl

Type: Double Displacement Reaction (Precipitation Reaction)

Activity 1.11: Oxidation of Copper

Procedure: Heat copper powder in a china dish

Observations:

Reaction: 2Cu + O₂ → 2CuO

Type: Oxidation Reaction

Group Activity: Identifying Reaction Types

Exothermic and Endothermic Reactions Experiment

Procedure: Measure temperature changes in four different beakers with various chemical interactions

Understanding Reaction Types

Main Types of Chemical Reactions

  1. Combination Reaction: Two or more substances combine to form a single product
  2. Decomposition Reaction: A single compound breaks down into multiple substances
  3. Displacement Reaction: A more reactive element replaces a less reactive element in a compound
  4. Double Displacement Reaction: Exchange of ions between two compounds